Ultra‐High Loading of Coal‐Derived Flash Graphene Additives in Epoxy Composites
نویسندگان
چکیده
Abstract Graphene has proved to be an exceptional reinforcing additive for composites, but the high cost of its synthesis largely prevented addition on industrial scales. Flash Joule heating provides a rapid, bulk‐scale method graphene from coal materials, such as metallurgical coke (MC), into coke‐derived flash (MCFG). Here, this work investigates properties graphene‐epoxy composites in higher nanofiller content regime than previously been reported literature. Composites with 20 50 wt% loading MCFG are prepared by combining diglycidyl ether bisphenol A epoxy precursor (DGEBA) and 1,5‐diamino‐2‐methylpentane. With 1:2 ratio MCFG:DGEBA, Young's modulus increases 92% 1:3 ratio, hardness 140%. At 1:4 compressive strength maximum strain increase 145% 61%, respectively. toughness 496%. Finally, at 1:1 GHG emissions, water consumption, energy consumption reduced 33%, 47%, 34%, As FG plummets, since it can produced very low materials like MC, milliseconds no solvent or water, prospects promising high‐loading use composites.
منابع مشابه
Ultrahigh Loading of Nanoparticles into Ordered Block Copolymer Composites
Phase selective, ultrahigh loading of nanoparticles into target domains of block copolymer composites was achieved by blending the block copolymer hosts with small molecule additives that exhibit strong interactions with one of the polymer chain segments and with the nanoparticle ligands via hydrogen bonding. The addition of D-tartaric acid to poly(ethylene oxide-block-tert-butyl acrylate) (PEO...
متن کاملBioinspired highly electrically conductive graphene–epoxy layered composites
Key Laboratory of Bio-inspired Smart Interfa Education, School of Chemistry and Enviro China. E-mail: [email protected]; Fax: +8 Science and Technology on Advanced Com Aeronautical Materials, AVIC Composites T China Key Laboratory for Biomechanics and Me School of Biological Science and Medical E P. R. China † Electronic supplementary information comments relevant to but not central to experime...
متن کاملThermoelectric Responsive Shape Memory Graphene/Hydro-Epoxy Composites for Actuators
A series of thermoelectric responsive shape memory hydro-epoxy (H-EP) composites filled with different contents of graphene were developed and characterized. Compared with traditional actuation materials, these novel shape memory composites exhibit attractive properties, such as light weight, large deformation, good processability and high response speed, making them good candidates for actuato...
متن کاملAtomistic simulations on multilayer graphene reinforced epoxy composites
We use molecular dynamics simulations to characterize multilayer graphene reinforced epoxy composites. We focus on two configurations, one where the graphene layers are parallel to polymer/graphene interface and a perpendicular case, and characterize the in situ curing process of the resin and the thermo-mechanical response of the composites. The yield stress of the composites under uniaxial lo...
متن کاملInfluence of microstructural features on thermal expansion coefficient in graphene/epoxy composites
In this paper, theoretical calculations were conducted to determine the coefficient of thermal expansion (CTE) based on the effective medium approach using Green's function method. The influences of microstructural features were investigated, including volume fraction, aspect ratio, and the orientation of graphene fillers. Calculated results demonstrated strong anisotropy of CTE when all graphe...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Macromolecular Materials and Engineering
سال: 2022
ISSN: ['1439-2054', '1438-7492']
DOI: https://doi.org/10.1002/mame.202200640